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Vishal Govind Rao

Vishal Govind Rao

PhD (IIT Kharagpur)

Assistant Professor, Department of Chemistry

Research Interest

Plasmonic photocatalysis; interfacial charge transfer dynamics; strategies for efficient solar energy utilization, and carbon dioxide reduction into hydrocarbon fuels

FB 422,
Department of Chemistry
IIT Kanpur,
Kanpur 208016

Specialization

Time Resolved and Single Molecule Spectroscopy, Raman Spectroscopy, Interface Science, Material Chemistry

Education

PhD, IIT Kharagpur

Teaching Area

Physical Chemistry

Spectroscopy, Instrumentation, and Material Chemistry.

Selected Publications

Chemical Requirement for Extracting Energetic Charge Carriers from Plasmonic Metal Nanoparticles to Perform Electron-Transfer Reactions, J. Am. Chem. Soc., 141, 643 (2019).
Catalytic Conversion of Solar to Chemical Energy on Plasmonic Metal Nanostructures, Nature Catalysis, 1, 656 (2018).
Probing Electric Field Effect on Covalent Interactions at a Molecule–Semiconductor Interface, J. Am. Chem. Soc., 138, 1536 (2016).
Inhomogeneous and Complex Interfacial Electron-Transfer Dynamics: A Single-Molecule Perspective, ACS Energy Lett., 1, 773 (2016).
Single-Molecule Interfacial Electron Transfer Dynamics of Porphyrin on TiO2 Nanoparticles: Dissecting Interfacial Electric Field and Electron Accepting State Density Dependent Dynamic, Chem. Commun., 51, 16821 (2015).

Professional Experience

Assistant Professor, IIT-Kanpur: April, 2019-present

Postdoctoral Research Fellow, University of Michigan, USA: Feb, 2017-Feb, 2019

Postdoctoral Research Associate, Bowling Green State University, Ohio, USA: June, 2013-Jan, 2017

Current Research

In a world where fossil fuel reserves are being rapidly depleted, solar energy remains the most promising source of alternative energy. Several approaches are being pursued to develop new strategies for efficient energy utilization. At the core of most of these strategies, is the optimization of photocatalytic efficiency of materials. Our lab seeks to understand the fundamental properties of photocatalytic materials that affect their catalytic efficiency. The broad aim of my group would be to probe/manipulate the interface dynamics of charge/energy transfer to improve the catalytic yield while ensuring the process remains cost effective. To achieve these goals, we will perform controlled synthesis of novel high-performance materials and investigate mechanistic details of catalytic reactions on functionalized metallic nanoparticle systems using a multi-technique approach to correlate fluorescence spectroscopy with electrochemistry and Raman spectroscopy. Such a multi-probed study will facilitate inspection of multiple-parameters with high chemical selectivity and wide temporal and spatial resolutions required to uncover complex charge transfer dynamics. With better understanding of these parameters, we can come up with energy efficient alternatives that can actually be implemented commercially, and not be confined to academic interests.